If you have air trapped in the system.. usually it's from opening the coolant system (I got a bubble when I changed the temp sender). You may not have a thermostat with a jiggle valve (it looks like a little BB in a cup at the top of the t/stat).
In addition to the other procedures to purge air, do this: Grab the upper radiator hose when the car is running and just keep squeezing and releasing it.. it'll force the air around and hopefully push it out too.
The neck of the radiator should have coolant almost to its top.
I usually just fill the overflow to the top, the coolant system knows how much should be in there and it'll kick out any extra if it has to.